By Sina Ebnesajjad
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Extra resources for Adhesives Technology Handbook, 2nd Edition
The adhesive bond is weak when two polymers are bonded at temperatures below the melting point of the polyoleﬁn. Bond strength increases sharply when the adhesion process takes place above the melting temperature of polyethylene (135˚C) and polypropylene (175˚C). 1 illustrates the bond strength (peel strength) as a function of bonding temperature. An inference can be made that at elevated temperatures, the interdiffusion of polyoleﬁns and butyl rubber increases, thus leading to higher bond strength.
Ebnesajjad, S. F. Ebnesajjad, Surface Preparation Techniques for Adhesive Bonding, William Andrew Publishing/Noyes, Norwich, NY, 2006. 10. Satas, D. A. , Marcel Dekker, New York, NY, 2001. 11. , Fundamentals of Adhesion, Plenum Press, New York, 2001. 12. S. H. , Fundamentals of Adhesion and Interfaces, Taylor & Francis, London, 1999. 13. , Plastics and adhesives as adhesives. A. , McGraw-Hill, New York, 2002. 14. , Int. J. , 13: 67, 1993. 15. V. P. Smilga, J. Appl. , 38: 4609, 1967. 16. V. P. Toporov, Physiochem.
Covalent chemical bonds can form across the interface and are likely to occur in cross-linked adhesives and thermoset coatings. This type of bond is usually the strongest and most durable. However, they require that mutually reactive chemical groups should exist. Some surfaces, such as previously coated surfaces, wood, composites, and some plastics, contain various functional groups that under appropriate conditions can produce chemical bonds with the adhesive material. There are ways to intentionally generate these conditions, such as by surface treatment of plastics with techniques like corona or ﬂame treatment.
Adhesives Technology Handbook, 2nd Edition by Sina Ebnesajjad